Level Graduate
Semester 2026/02
Schedule Mon/Wed 10:40-12:20

STATISTICAL MECHANICS

Entropy, Information, and Quantum Systems

Graduate Program in Physics — UERJ

Prof. Marcelo Santos Guimarães

2nd semester 2026 — Mondays and Wednesdays, 10:40–12:20 — 1h40 per class

Course Overview

This is a graduate course in equilibrium statistical mechanics. It develops the standard machinery — ensembles, classical and quantum gases, phase transitions, the Ising model, and the renormalization group — and then uses information theory and quantum information to clarify what that machinery means.

The material is organized into 29 lectures across seven modules, interleaved with three in-person written assessments, running from 10 August to 9 December 2026.

Lectures include short concept questions that the whole class answers and then discusses in pairs. These are not graded, but they are where the vocabulary used throughout the course — deciding whether a given claim is exact, a thermodynamic-limit statement, a controlled approximation, or a heuristic — is actually practised.

Learning Outcomes

By the end of the course, a student should be able to:

  • derive the microcanonical, canonical, and grand-canonical ensembles and move between their thermodynamic potentials;
  • compute fluctuations and response functions, and state when ensembles become equivalent;
  • distinguish thermodynamic, Boltzmann, Gibbs, Shannon, von Neumann, entanglement, and Rényi entropies;
  • use classical and quantum relative entropy, mutual information, and maximum-entropy inference in statistical-mechanical problems;
  • explain why microscopic reversibility does not by itself yield macroscopic entropy increase;
  • solve standard classical and quantum-gas problems, including degenerate Fermi gases and Bose–Einstein condensation;
  • analyze simple phase transitions through Landau theory and the Ising model;
  • explain coarse graining, fixed points, relevance, and universality in the renormalization group;
  • state clearly whether a result is exact, a thermodynamic-limit statement, a controlled approximation, a model-specific example, or a heuristic argument.

Main References

  • [Kardar-P] M. Kardar, Statistical Physics of Particles, Cambridge University Press, 2007.
  • [PB] R. K. Pathria & P. D. Beale, Statistical Mechanics, 3rd ed., Elsevier, 2011.
  • [Reichl] L. E. Reichl, A Modern Course in Statistical Physics, 4th ed., Wiley, 2016.
  • [Kardar-F] M. Kardar, Statistical Physics of Fields, Cambridge University Press, 2007 — for phase transitions and renormalization.

Additional references:

  • [CT] T. M. Cover & J. A. Thomas, Elements of Information Theory, 2nd ed., Wiley, 2006.
  • [NC] M. A. Nielsen & I. L. Chuang, Quantum Computation and Quantum Information, Cambridge University Press, 2000.
  • [Wilde] M. M. Wilde, Quantum Information Theory, 2nd ed., Cambridge University Press, 2017.
  • [Witten] E. Witten, “A Mini-Introduction to Information Theory,” Rivista del Nuovo Cimento 43 (2020), arXiv:1805.11965.
  • [Tong] D. Tong, Lectures on Statistical Physics — a concise standard route through ensembles, gases, and phase transitions.
  • [Touchette] H. Touchette, “The large deviation approach to statistical mechanics,” Physics Reports 478 (2009) — large deviations and ensemble equivalence.
  • [Seifert] U. Seifert, “Stochastic thermodynamics, fluctuation theorems and molecular machines,” Rep. Prog. Phys. 75 (2012) — entropy production and nonequilibrium work.

Assessment System

Grades come only from individual, in-person written assessments. There are three, weighted 30% / 30% / 40%.

AssessmentDateWeightCoverage
Assessment 116/09 (Wed)30%Modules I–II: thermodynamics, entropy, probability, ensembles, maximum entropy
Assessment 204/11 (Wed)30%Modules III–IV: classical systems, irreversibility, information thermodynamics, quantum entropy, Landauer’s principle
Assessment 309/12 (Wed)40%Modules V–VII: quantum gases, phase transitions, Ising, renormalization + a short cumulative entropy-synthesis problem

Structure of each assessment

Every assessment has the same two parts.

Part A — Referee exercise (40 points). You receive a short draft derivation, competently written and mostly correct, containing a small number of substantive defects: statements that are wrong, or that claim a stronger status than they possess. For each defect you must

  1. locate it — quote the sentence or equation;
  2. diagnose it — say what is wrong, and name the assumption, limit, or approximation that has been misused or hidden;
  3. repair it — give the corrected statement together with its status: exact, thermodynamic-limit, controlled approximation, mean field, model-specific exact result, or heuristic.

Not everything unusual is wrong: flagging a correct statement costs points, so justify what you flag.

Part B — Calculations (60 points). Two problems of the same kind as the exercises in the lecture notes.

Conditions. One 1h40 meeting per assessment; individual work, in person; one handwritten double-sided A4 formula sheet; no books, internet, or electronic devices.

Practice

The lecture notes contain exercises for self-study. They are not submitted and not graded: the point of the assessments is not to reproduce a solution but to diagnose an argument and state precisely what it does and does not establish. Selected problems can be discussed in optional office hours.

Module Summary

ModuleThemeLecturesDates
IThermodynamics and the meaning of entropy410–19 Aug
IIProbability, ensembles, and inference624 Aug–14 Sep
IIIClassical systems and irreversibility621 Sep–7 Oct
IVInformation thermodynamics and quantum entropy414–26 Oct
VIdeal quantum gases49–18 Nov
VIPhase transitions and the Ising model323–30 Nov
VIIRenormalization and final synthesis22–7 Dec
Total29 lectures10 Aug–7 Dec (+ 3 assessments)

Reading map

The lecture notes are organized into twelve chapters. Modules and chapters do not correspond one to one — Module IV in particular draws on three different chapters.

ModuleLecturesChapters in the notes
I1–41. Thermodynamics and the macroscopic entropy
II5–102. Probability, information, and typicality (probability; maximum entropy; large deviations) · 3. Equilibrium ensembles
III11–164. Classical gases and interacting particles · 5. Microscopic dynamics and irreversibility
IV17–202. (Shannon entropy, relative entropy, mutual information) · 6. Information is physical · 7. Quantum states, entropy, and equilibrium
V21–248. Identical particles and ideal quantum gases
VI25–279. Phase transitions, order parameters, and scaling · 10. The Ising model
VII28–2911. Renormalization and universality · 12. One word, several entropies

Each chapter opens with a box naming the lectures it covers, and markers in the margin of the text show where one lecture ends and the next begins.

Detailed Calendar

The teaching period runs from 10 August to 12 December, on Mondays and Wednesdays. Three meetings fall on official holidays (7 September, 12 October, 2 November); 28 October (Public Servants’ Day) is kept as a reserve date until the Institute confirms whether classes occur.

#DateMod.TypeTopic and scope
110/08 MonILectureWhy statistical mechanics? Macroscopic regularity, equilibrium, microstates and macrostates; the semester-long entropy map
212/08 WedILectureLaws of thermodynamics. Heat, work, reversible and irreversible processes; Carnot theorem and absolute temperature
317/08 MonILectureThermodynamic entropy. Clausius definition, second-law inequalities, entropy production, third law and residual entropy
419/08 WedILectureThermodynamic structure. Fundamental relation, extensivity, concavity, Euler and Gibbs–Duhem relations, Legendre transforms and stability
524/08 MonIILectureProbability for many-body systems. Random variables, combinatorics, law of large numbers, central limit theorem, concentration and typicality
626/08 WedIILectureMicrocanonical ensemble. Phase-space volume, density of states, Boltzmann entropy, temperature, pressure, ideal gas and the Gibbs paradox
731/08 MonIILectureCanonical ensemble. Derivation from a reservoir, Gibbs distribution, partition function and Gibbs entropy
802/09 WedIILectureFree energy, fluctuations, and response. Energy fluctuations, heat capacity, susceptibilities, convexity and stability
—07/09 Mon—HolidayNo class: Independence Day
909/09 WedIILectureGrand-canonical ensemble. Chemical potential, particle-number fluctuations, grand potential and ensemble equivalence
1014/09 MonIILectureMaximum entropy and large deviations. Constrained inference, exponential families, Legendre–Fenchel transforms and the thermodynamic limit
—16/09 WedI–IIExamExam 1
1121/09 MonIIILectureClassical ideal gas. Maxwell distribution, equipartition, Sackur–Tetrode entropy and the classical dilute limit
1223/09 WedIIILectureMolecular degrees of freedom. Harmonic solids, rotations and vibrations of diatomic gases; classical limits and quantum corrections
1328/09 MonIIILectureInteracting gases. Mayer expansion, second virial coefficient, van der Waals equation and the range of the dilute-gas approximation
1430/09 WedIIILectureClassical phase-space mechanics. Liouville theorem, invariant measures, ergodicity, mixing, coarse graining and what each does not prove
1505/10 MonIIILectureStochastic entropy production. Master equations, detailed balance, stationary currents, local detailed balance and relative-entropy contraction
1607/10 WedIIILectureKinetic theory and fluctuation relations. Boltzmann’s $H$-theorem, molecular chaos, Loschmidt’s objection, Jarzynski’s equality and their assumptions
—12/10 Mon—HolidayNo class: Nossa Senhora Aparecida
1714/10 WedIVLectureInformation and correlations. Shannon entropy, conditional entropy, relative entropy, mutual information and data processing
1819/10 MonIVLectureInformation is physical. Maxwell’s demon, measurement, feedback, erasure and Landauer’s bound
1921/10 WedIVLectureQuantum entropy and equilibrium. Density operators, von Neumann entropy, quantum relative entropy, Gibbs states and the free-energy identity
2026/10 MonIVLectureComposite quantum systems. Partial trace, purification, subadditivity, mutual information, entanglement entropy and Rényi entropies
—28/10 WedIVReservePublic Servants’ Day. No new required content; if classes occur, used for worked problems, catch-up, and Exam 2 review
—02/11 Mon—HolidayNo class: All Souls’ Day
—04/11 WedIII–IVExamExam 2
2109/11 MonVLectureIdentical particles and occupation numbers. Fock space, Bose and Fermi statistics, grand partition functions and the classical limit
2211/11 WedVLectureIdeal Fermi gas. Fermi energy, zero-temperature equation of state, Sommerfeld expansion and low-temperature heat capacity
2316/11 MonVLectureIdeal Bose gas. Bose–Einstein condensation, dimensional dependence, critical temperature and condensate fraction
2418/11 WedVLecturePhoton gas and synthesis of ideal gases. Blackbody thermodynamics; comparison of Maxwell–Boltzmann, Fermi–Dirac and Bose–Einstein regimes
2523/11 MonVILecturePhase transitions. Thermodynamic singularities, order parameters, spontaneous symmetry breaking, Landau free energy and mean-field limits
2625/11 WedVILectureIsing model I. One-dimensional transfer matrix, absence of a finite-temperature transition, correlations and correlation length
2730/11 MonVILectureIsing model II. Mean-field theory, the two-dimensional square lattice (duality and Onsager’s result), Monte Carlo sampling and finite-size scaling
2802/12 WedVIILectureRenormalization group I. Coarse graining and rescaling, the exact one-dimensional Ising decimation, coupling flow, fixed points, relevant and irrelevant operators
2907/12 MonVIILectureRenormalization group II and entropy synthesis. Critical exponents from RG eigenvalues, power counting and the $\epsilon$-expansion, universality, entropy under coarse graining, entanglement near criticality, final map of entropy concepts
—09/12 WedV–VIIExamExam 3

Closeout: classes officially end 12/12; a replacement or final exam may be held on 14/12; corrections and grade review 15–16/12; final grades released by 17/12.

Calendar Summary

MilestoneDate
First lecture10/08 (Mon)
Holidays (no class)07/09, 12/10, 02/11
Exam 1 (Modules I–II)16/09 (Wed)
Reserve date28/10 (Wed)
Exam 2 (Modules III–IV)04/11 (Wed)
Last regular lecture07/12 (Mon)
Exam 3 (Modules V–VII)09/12 (Wed)
Replacement / final exam14/12 (Mon)
Final grades17/12 (Thu)

Lecture Notes

#TopicFile
1Course notesstatistical-mechanics2026-v3.pdf

Problem Sets

#TopicFileDeadline
1Referee exercise — practice for Assessment 1 (not graded, nothing to hand in)practice-referee-exercise-modules-I-II.pdf—
1Referee exercise — annotated key to the practice sheetpractice-referee-exercise-modules-I-II-key.pdf—

Exam Dates

ExamDateNote
Assessment 116/09/2026Modules I–II (thermodynamics, entropy, probability, ensembles, maximum entropy) — 30%
Assessment 204/11/2026Modules III–IV (classical systems, irreversibility, information thermodynamics, quantum entropy) — 30%
Assessment 309/12/2026Modules V–VII (quantum gases, phase transitions, Ising, renormalization) + cumulative synthesis — 40%
Replacement / Final14/12/2026If required, according to the program's rules
↑